Lignin bioconversion into valuable products: fractionation, depolymerization, aromatic compound conversion, and bioproduct formation

Catalytic conversion of lignin pyrolysis model compound- guaiacol and its kinetic model including coke formation

Lignin is the most difficult to be converted and most easy coking component in biomass catalytic pyrolysis to high-value liquid fuels and chemicals. Catalytic conversion of guaiacol as a lignin model compound was conducted in a fixed-bed reactor over ZSM-5 to investigate its conversion and coking behaviors. The effects of temperature, weight hourly space velocity (WHSV) and partial pressure on ...

Waste Paper - Promissing Feedstock for Bioethanol Production

Modern approach to utilization of non-edible biomass is its conversion to glucose, and the following fermentation of the sugar into final bioproducts. Among various biomass types, the waste of office paper is distinguished by increased content of cellulose and negligible content of lignin; therefore it can be a suitable feedstock for bioconversion into valuable bioproduct, e.g. ethanol. An adva...

Redox Catalysis Facilitates Lignin Depolymerization

Lignin is a recalcitrant and underexploited natural feedstock for aromatic commodity chemicals, and its degradation generally requires the use of high temperatures and harsh reaction conditions. Herein we present an ambient temperature one-pot process for the controlled oxidation and depolymerization of this potent resource. Harnessing the potential of electrocatalytic oxidation in conjugation ...

Free radical reaction promoted by ionic liquid: a route for metal-free oxidation depolymerization of lignin model compound and lignin.

Ionic liquid 1-benzyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BnMIm][NTf2]) can promote the generation of the ˙OOH free radical and thereby efficiently transformed the β-O-4 lignin model compound 2-phenoxyacetophenone into benzoic acid and phenol using O2 as the oxidant. Furthermore, the IL-based metal-free catalytic system can also depolymerize other lignin model compounds and ...

Bioconversion of Hemicellulose from Sugarcane Biomass Into Sustainable Products